辽河坳陷滩海东部地区天然气地球化学特征 及有机热成因-无机成因双源模式

作    者:胡英杰,刘兴周,黄双泉,蔡国钢,王延山,李金有,杨光达,侯拓,张东伟
单    位:中国石油辽河油田公司
基金项目:
摘    要:
辽河坳陷滩海东部地区葵探1井获得天然气重大突破,其侏罗系、古近系天然气的甲烷碳同位素组成(δ13C1)差 异大,确定天然气成因与气源岩对于评价天然气资源潜力及选择勘探目标具有重要意义。系统分析了滩海东部地区古 近系东营组、沙河街组三段和侏罗系小东沟组3套含气层系的天然气组分、稳定碳同位素组成等地球化学特征,对天然 气成因和来源进行探讨。滩海东部地区发育有机热成因气和无机成因气2种类型:①古近系东营组和沙三段天然气为 煤型有机热成因气,成分以甲烷为主,干燥系数介于0.789~0.949,δ13C1值主要在-35‰左右。主要气源岩为盖州滩洼陷 沙三中下亚段泥岩,Ro在0.77%~1.59%之间。中浅层东营组天然气成熟度显著高于同深度泥岩,表明天然气来源于深 部地层;而深层沙河街组三段天然气成熟度与同深度泥岩差异不大,表明天然气以原地聚集为主。②侏罗系小东沟组 天然气为无机成因气,干燥系数平均值为0.991,δ13C1值>-20‰;推测东营末期深大断裂大规模走滑活动沟通地壳深部 与地幔,费托合成的无机天然气沿断裂带运聚成藏。盖州滩洼陷沙三段成熟烃源岩分布区与营口—佟二堡走滑断裂带 是分别探索有机热成因型与无机成因型天然气的有利目标区带。
关键词:碳同位素;气体组分;热成因气;无机成因气;费托合成;滩海东部地区;辽河坳陷

Geochemical characteristics of natural gas and dual-source pattern of thermogenic gas and inorganic gas in the eastern offshore of Liaohe Depression

Author's Name: HU Yingjie, LIU Xingzhou, HUANG Shuangquan, CAI Guogang, WANG Yanshan, LI Jinyou, YANG Guangda, HOU Tuo, ZHANG Dongwei
Institution: 
Abstract:
In 2022, a significant gas breakthrough was achieved in the key exploration well (Kuitan-1) located in the Kuihuadao structural belt of the eastern offshore, Liaohe Depression, with high-productivity gas flows in Dongying Formation, Shahejie Member 3, and Jurassic Xiaodonggou Formation. It is worth noting that there are significant differences in methane carbon isotope composition (δ13C1) between the Mesozoic and Cenozoic natural gas formations. Determining the origin of natural gas and its source rock is significant for assessing the potential of natural gas resources and selecting exploration targets. This paper systematically analyzes geochemical data such as the components and stable carbon isotope composition of natural gas samples from the three gas-bearing strata. The results indicate that there are organic thermogenic gas and inorganic gas in the eastern offshore: (1) The natural gas in the Dongying Formation and Shahejie Formation belongs to the coal-type organic thermogenic gas, mainly consisting of methane, the dryness coefficient is at the range of 0.789-0.949. δ13C1 is mainly around -35‰. Natural gas originates from the mature mudstone in the middle and lower part of Shahejie Formation in Gaizhoutan sag, and accumulates during the late Dongying-Minghuazhen periods. According to the empirical formula, Ro of gas source rock ranges from 0.77% to 1.59%. There is a clear indication of migration effects for natural gas in the middle and shallow Dongying Formation, with clearly higher Ro of gas source rock than the mudstone at the same depth. In the deep Shahejie Member 3, it accumulates in situ or with short distance migration, indicated by the similar or slightly higher Ro of gas source rock than the mudstone at the same depth. (2) The natural gas in Jurassic Xiaodonggou Formation is of inorganic origin. It has an average dryness coefficient of 0.991 and is characterized by extremely heavy methane carbon isotope (δ13C1>-20‰). It’s inferred that the natural gas originates from Fischer-Tropsch synthesis in the deep crust or mantle, migrates and accumulates along the deep-seated fault with strike-slip activity during the late Dongying period. These natural gas reservoirs of two genetic types have obvious vertical separation and different accumulation processes. Plays around the Shahejie mature source rocks in the Gaizhoutan sag and the Yingkou-Tong'erbu strike-slip zone are favorable to organic thermogenic gas and inorganic gas respectively.
Keywords: carbon isotope; gas components; thermogenic gas; inorganic gas; Fischer-Tropsch synthesis; eastern off⁃ shore; Liaohe Depression
投稿时间: 2024-04-07  
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