四川盆地长宁—威远页岩气示范区下志留统龙马溪组泥页岩吸附特征及影响因素分析

作    者:李笑天1,2,潘仁芳1,2,鄢 杰3,李夏露4,李晓薇5,胡 斌6
单    位:(1油气资源与勘探技术教育部重点实验室;2长江大学地球科学学院;3 中国石油西南油气田分公司蜀南气矿;4 中海石油(中国)有限公司湛江分公司研究院;5中国石化中原油建工程有限公司;6长城钻探工程有限公司录井公司)
基金项目:国家自然科学基金“页岩油、气甜点构成要素比较研究”(编号:41472123)资助
摘    要:
针对四川盆地长宁—威远页岩气示范区志留系龙马溪组泥页岩吸附气量大(70%~80%)的特性,对该页岩气区11口井龙马溪组优质页岩段的岩心样品作X射线衍射分析、扫描电镜和等温吸附分析测试,结合大量泥页岩含气量实测数据,统计分析及评价表明:研究区地层因素中,生烃条件如总有机碳含量(0.17%~4.3%)、有机质类型(Ⅰ、Ⅱ1型)和成熟度(2.4%~3.0%),以及储层条件如矿物成分、孔隙体积(3%~6%)、孔隙结构(中孔为主)和湿度,主要是通过改变页岩气生成量和吸附活性表面的大小而产生影响;外部因素如温度和压力主要是通过改变气体分子的活化能和结合能而对泥页岩吸附能力产生一定的影响。
关键词:四川盆地;长宁;威远;龙马溪组; 页岩气;吸附特征;影响因素

Adsorptivity and Influential Factors of Lower Silurian Longmaxi Gas-bearing Shale in Changning-Weiyuan Area, Sichuan Basin

Author's Name: Li Xiaotian,Pan Renfang,Yan Jie,Li Xialu,Li Xiaowei,Hu Bin
Institution: Department of Geosciences, Yangtze University
Abstract:
According to rock analysis of X- ray diffraction, scanning electron microscopy and isothermal adsorption experiments on Lower Silurian Longmaxi shale cores samples from 11 gas wells in Changning-Weiyuan area in the southern part of Sichuan Basin, the adsorptivity and its influential factors are statistically analyzed. Combined with a large number of measured data of gas content in shale, it is shown that stratigraphic factors commonly exert their influences on adsorption through changing the gas generation amount and the extent of adsorbing active surface area in shale. The stratigraphic factors mainly include hydrocarbon generation conditions such as TOC(0.17%~4.3%), type of organic matter (Type-Ⅰ or Type-Ⅱ1) and maturity(2.4%~3.0%), and reservoir conditions such as mineral composition, pore volume(3.0%~6.0%) and structure(mostly mesopores) and humidity. External factors, such as pressure and temperature, exert their definite influences on the adsorption capacity of Longmaxi shale through changing activation energy and binding energy of gas moleculars.
Keywords: Lower Silurian; Longmaxi Fm.; Gas shale; Adsorption characteristics; Influential factor; Changning; Weiyuan
投稿时间: 2015-08-06  
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