湘西北地区下志留统龙马溪组页岩矿物成分特征及意义

作    者:刘 亢1,曹代勇1,林中月1,王玉芳2
单    位:(1中国矿业大学(北京)地球科学与测绘工程学院; 2中国地质调查局油气资源调查中心)
基金项目:受中国地质调查局项目“页岩气有利区块调查与优选评价”(编号:12120114054101)资助
摘    要:
运用X射线全岩衍射和扫描电镜等技术,对湘西北地区下志留统龙马溪组的页岩矿物组成进行了定性和定量分析。龙马溪组页岩主要矿物成分是石英(48.1%)、黏土矿物(34.0%)和长石(11.5%),且含有少量方解石、白云石和黄铁矿等;黏土矿物呈伊利石、有序的伊/蒙混层和少量绿泥石以及微量高岭石的组合特征,其中伊利石和伊/蒙混层含量较高,分别达到64.7%和21.7%,反映出龙马溪组页岩达到晚成岩作用阶段。龙马溪组处于浅水陆棚向深水陆棚过渡的沉积环境,页岩有机质易于富集和保存。页岩岩心样品脆性矿物含量分布在34.4%~79.6%之间,平均脆性指数达65.4%,具备较好的压裂改造条件。与周边焦石坝页岩气田等相比,龙马溪组页岩矿物组成具有相似性,反映湘西北具备页岩气勘探开发的地质潜力。
关键词:湘西北;志留纪;龙马溪组;页岩气;矿物成分

Characteristics and Significance of Mineral Compositions of Shale in Lower Silurian Longmaxi Formation, Northwestern Hu’nan

Author's Name: Liu Kang, Cao Daiyong, Lin Zhongyue, Wang Yufang
Institution: China University of Mining & Technology(Beijing)
Abstract:
Using X-ray diffraction (XRD) and scanning electron microscopy (SEM) techniques, the qualitative and quantitative analyses of the mineral composition of shale in the Lower Silurian Longmaxi Formation in northwestern Hu’nan were conducted. The main mineral components of the shale are quartz (48.1%), clay minerals(34.0%), and feldspar (11.5%), containing small amounts of calcite, dolomite, and pyrite. The content of illite and illite/montmorillonite mixed layer in clay minerals is relatively high, averaging 64.7% and 21.7% respectively. The clay mineral is the combination of illite, ordered illite/montmorillonite, and a small amount of chlorite and trace kaolinite, reflecting that the Longmaxi Formation shale reached the stage of late diagenesis. In a transitional sedimentary environment from shallow-water to deep-water continental shelf, the shale organic matter of Longmaxi Formation is easy to be enriched and preserved. The content of brittle minerals in shale core samples ranged from 34.4% to 79.6%, and the average brittleness index reached 65.4%, showing a good condition for fracturing transformation. Compared with the surrounding Jiaoshiba shale gas field, the composition of the shales in the Longmaxi Formation is similar, reflecting the geological potential of shale gas in northwestern Hu’nan.
Keywords: Silurian; Longmaxi Formation; Shale gas; Mineral composition; Northwestern Hu’nan
投稿时间: 2016-12-13  
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